Chemistry (9476)

9 个单元 · 63 个章节

免费 Chemistry (9476) 学习笔记,适合 GCE A-Level - Higher 2 (H2) 学生。每个章节都覆盖一个重点主题,并附例题与可延伸到 thinka app 的练习提示。

Atomic Structure, the Periodic Table and Transition Elements

  • The nucleus of the atom: neutrons and protons, isotopes, proton and nucleon numbers

  • Electrons: electronic energy levels, ionisation energies, atomic orbitals, extranuclear structure

  • The Periodic Table

  • General physical and characteristic chemical properties of the first set of transition elements, scandium to copper

  • Colour of complexes

Chemical Bonding and Structure

  • Ionic bonding, metallic bonding, covalent bonding and co-ordinate (dative covalent) bonding

  • Shapes of simple molecules and bond angles

  • Bond polarities and polarity of molecules

  • Intermolecular forces, including hydrogen bonding

  • Bond energies and bond lengths

  • Lattice structure of solids

  • Bonding and physical properties

The Gaseous State and Stoichiometry

  • Ideal gas behaviour and deviations from it

  • pV = nRT and its use in determining a value for Mr

  • Dalton’s Law and its use in determining the partial pressures of gases in a mixture

  • Relative masses of atoms and molecules

  • The mole, the Avogadro constant

  • The calculation of empirical and molecular formulae

  • Reacting masses and volumes (of solutions and gases)

Chemical Energetics and Reaction Kinetics

  • Enthalpy changes: ΔH, of formation; combustion; hydration; solution; neutralisation; atomisation; bond energy; lattice energy; electron affinity

  • Hess’ Law, including Born-Haber cycles

  • Entropy and Free Energy

  • Simple rate equations; orders of reaction; rate constants

  • Concept of activation energy

  • Effect of concentration, temperature, and catalysts on reaction rate

  • Homogeneous and heterogeneous catalysis

  • Enzymes as biological catalysts

Chemical Equilibria and Aqueous Solutions

  • Chemical equilibria: reversible reactions; dynamic equilibrium

  • Arrhenius, Brønsted-Lowry and Lewis theories of acids and bases

  • Acid dissociation constants, Ka and the use of pKa

  • Base dissociation constants, Kb and the use of pKb

  • The ionic product of water, Kw

  • pH: choice of pH indicators

  • Buffer solutions

  • Solubility product; the common ion effect and complex ion formation

Organic Chemistry: Foundations

  • Functional groups and the naming of organic compounds

  • Empirical, molecular and structural formulae

  • Shapes of organic molecules; σ and π bonds

  • Isomerism: constitutional (structural); cis-trans; enantiomerism

  • Common terms for organic reactions and reactivities

  • Reactivity of some classes of compounds and their characteristic organic reaction mechanisms

Hydrocarbons and Halogen Derivatives

  • Alkanes (exemplified by ethane)

  • Alkenes (exemplified by ethene)

  • Arenes (exemplified by benzene and methylbenzene)

  • Hydrocarbons as fuels

  • Halogenoalkanes

  • Relative strength of the carbon-halogen bond

  • Unreactivity of halogenoarenes

Alcohols, Carbonyl Compounds and Carboxylic Acids

  • Alcohols (exemplified by ethanol)

  • Phenol

  • Aldehydes (exemplified by ethanal)

  • Ketones (exemplified by propanone and phenylethanone)

  • Carboxylic acids (exemplified by ethanoic acid and benzoic acid)

  • Acyl chlorides (exemplified by ethanoyl chloride)

  • Esters (exemplified by ethyl ethanoate and phenyl benzoate)

Nitrogen Compounds, Polymers and Electrochemistry

  • Amines (exemplified by ethylamine and phenylamine)

  • Amides (exemplified by ethanamide)

  • Amino acids (exemplified by aminoethanoic acid)

  • Addition and condensation of polymers

  • Proteins

  • Biodegradability of poly(alkenes), polyesters and polyamides

  • Redox processes and electrode potentials

  • Electrolysis

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