(a) Show that the Boltzmann factor \(e^{-E_g/kT}\) for this transition at a temperature \(T = 293\text{ K}\) is approximately \(1.2 \times 10^{-19}\).
(b) A temperature-sensitive circuit requires the Boltzmann factor to increase by exactly a factor of 10.0 to trigger a threshold alarm. Calculate the temperature, in kelvin, at which the Boltzmann factor is exactly 10.0 times its value at \(293\text{ K}\).
(Boltzmann constant \(k = 1.38 \times 10^{-23}\text{ J K}^{-1}\), elementary charge \(e = 1.60 \times 10^{-19}\text{ C}\))
PastPaper.showAnswersPastPaper.hideAnswers
PastPaper.workedSolution
\(E_g = 1.1 \times 1.60 \times 10^{-19}\text{ J} = 1.76 \times 10^{-19}\text{ J}\).
At \(T = 293\text{ K}\), calculate the thermal energy term \(kT\):
\(kT = 1.38 \times 10^{-23}\text{ J K}^{-1} \times 293\text{ K} = 4.043 \times 10^{-21}\text{ J}\).
Calculate the exponent:
\(\frac{E_g}{kT} = \frac{1.76 \times 10^{-19}}{4.043 \times 10^{-21}} \approx 43.53\).
Calculate the Boltzmann factor:
\(e^{-43.53} \approx 1.25 \times 10^{-19}\), which is approximately \(1.2 \times 10^{-19}\).
(b) Let \(\text{BF}_1 = 1.248 \times 10^{-19}\) and the target factor \(\text{BF}_2 = 1.248 \times 10^{-18}\).
Set up the equation for the new temperature \(T_2\):
\(e^{-E_g / k T_2} = 1.248 \times 10^{-18}\)
Take the natural logarithm of both sides:
\(-\frac{E_g}{k T_2} = \ln(1.248 \times 10^{-18}) \approx -41.225\)
Solve for \(T_2\):
\(T_2 = \frac{E_g}{41.225 \times k} = \frac{1.76 \times 10^{-19}}{41.225 \times 1.38 \times 10^{-23}} \approx 309.37\text{ K}\).
Rounded to 3 significant figures, \(T_2 = 309\text{ K}\).
PastPaper.markingScheme
- Convert eV to J: \(1.76 \times 10^{-19}\text{ J}\) [1 mark].
- Calculate \(kT\) at \(293\text{ K}\): \(4.04 \times 10^{-21}\text{ J}\) [1 mark].
- Compute exponential factor to show value close to \(1.2 \times 10^{-19}\) [1 mark].
(b) [5 marks total]:
- Identify the new Boltzmann factor value \(= 1.25 \times 10^{-18}\) [1 mark].
- Set up logarithmic relationship: \(\ln(\text{BF}_2) = -E_g / k T_2\) [1 mark].
- Rearrange equation to make \(T_2\) the subject [1 mark].
- Substitute correct values including \(k\) and \(E_g\) [1 mark].
- Obtain final temperature in range \(309\text{ K}\) to \(310\text{ K}\) [1 mark].
[1.67 marks reserved for consistent unit usage and correct significant figures across both parts].