(a) Outline the role of stratospheric ozone in absorbing ultraviolet (UV) radiation. [2]
(b) Describe the chemical process by which chlorofluorocarbons (CFCs) destroy stratospheric ozone. [3]
(c) Explain two reasons why the Montreal Protocol has been more successful in achieving its goals than international agreements targeting greenhouse gases, such as the Kyoto Protocol or Paris Agreement. [3]
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解題
(b) When CFCs reach the stratosphere, intense UV radiation causes photolysis, breaking the carbon-chlorine bond to release a free chlorine radical: CF2Cl2 + UV -> CF2Cl + Cl. The highly reactive chlorine radical reacts with ozone: Cl + O3 -> ClO + O2. Chlorine monoxide then reacts with monoatomic oxygen to release the chlorine radical again: ClO + O -> Cl + O2. This creates a catalytic cycle where chlorine is not consumed and can repeatedly destroy ozone.
(c) The success of the Montreal Protocol compared to climate agreements stems from:
1. Industry Cooperation: Chemical companies (like DuPont) were able to patent substitutes (HCFCs/HFCs), meaning compliance did not threaten their survival.
2. Simpler Source Regulation: Ozone-depleting substances were produced by a limited number of factories for specific uses (refrigeration, aerosols), whereas greenhouse gases are deeply embedded in energy, transport, and agriculture worldwide.
3. Direct Public Health Threat: The direct link between ozone depletion and immediate personal risks (skin cancer) drove rapid political action, unlike the more diffuse and long-term threat of climate change.
評分準則
- 1 mark for identifying that stratospheric ozone absorbs UV-B / UV-C radiation.
- 1 mark for linking this absorption to the prevention of biological harm (e.g., DNA damage, skin cancer, cataracts, or damage to crops/phytoplankton).
(b) Award up to 3 marks:
- 1 mark for explaining that UV radiation breaks down CFCs to release highly reactive chlorine atoms/radicals.
- 1 mark for showing the reaction of chlorine with ozone to produce chlorine monoxide and oxygen.
- 1 mark for explaining that the chlorine atom is regenerated/acts as a catalyst to destroy more ozone molecules.
(c) Award up to 3 marks:
- Max 2 marks for explaining Reason 1 (e.g., availability of substitutes / low economic impact of transition compared to fossil fuels).
- Max 2 marks for explaining Reason 2 (e.g., concentrated industry sector/fewer stakeholders to regulate compared to the entire global energy system).
- Note: To achieve full marks, at least one point must clearly contrast the CFC phase-out with the difficulties of greenhouse gas mitigation.