What is the correct definition of activation energy, \( E_a \)?
Cambridge International A Level · Chemistry (9701)
Reaction kinetics (AS):練習問題
その場で採点される選択問題 5 問と、解説つきの記述問題 5 問。すべて「Reaction kinetics (AS)」からの出題です。
The decomposition of a reactant X follows first-order kinetics. If the initial concentration of X is \(0.80 \text{ mol dm}^{-3}\) and its half-life is 20 minutes, what will the concentration of X be after 60 minutes?
In the oxidation of iodide ions by peroxodisulfate ions, \( S_2O_8^{2-} + 2I^- \to 2SO_4^{2-} + I_2 \), the reaction is catalysed by \( Fe^{2+}(aq) \).
Which set of equations correctly represents the homogeneous catalysis mechanism?
In the reaction between methane and chlorine, the first step is the homolytic fission of the \(Cl-Cl\) bond by ultraviolet light to form chlorine radicals. Which term best describes the minimum energy required for this specific step to occur effectively?
The reaction between hydrogen and nitrogen(II) oxide follows the rate equation: \( \text{rate} = k[NO]^2[H_2] \).
The following mechanism is proposed:
Step 1: \( 2NO \rightleftharpoons N_2O_2 \) (fast equilibrium)
Step 2: \( N_2O_2 + H_2 \to N_2O + H_2O \) (slow)
Step 3: \( N_2O + H_2 \to N_2 + H_2O \) (fast)
Why is the reaction second-order with respect to NO?
Define the term activation energy, \(E_a\), for a chemical reaction.
まず自分で答えを書いてから、解説と照らし合わせましょう。
Using the Boltzmann distribution, explain qualitatively why a small increase in temperature leads to a significant increase in the rate constant, \( k \).
まず自分で答えを書いてから、解説と照らし合わせましょう。
Describe the specific role of adsorption and desorption in the catalytic removal of oxides of nitrogen using a platinum-based catalytic converter in car engines.
まず自分で答えを書いてから、解説と照らし合わせましょう。
(a) Define the term rate of reaction. [1]
(b) Use the collision theory to explain why increasing the temperature of a reaction mixture increases the rate of reaction. [3]<\/p>
まず自分で答えを書いてから、解説と照らし合わせましょう。
The reaction between reactant X and reactant Y was studied at \(298\text{ K}\). The following experimental data were obtained:
| Experiment | Initial [X] / \(\text{mol dm}^{-3}\) | Initial [Y] / \(\text{mol dm}^{-3}\) | Initial rate / \(\text{mol dm}^{-3}\text{ s}^{-1}\) |
|---|---|---|---|
| 1 | 0.150 | 0.100 | \(1.20 \times 10^{-4}\) |
| 2 | 0.300 | 0.100 | \(4.80 \times 10^{-4}\) |
| 3 | 0.300 | 0.200 | \(9.60 \times 10^{-4}\) |
(a) Deduce the order of reaction with respect to X and the order of reaction with respect to Y. Show your reasoning. [2]
(b) Construct the rate equation for this reaction. [1]
(c) Calculate the value of the rate constant, \(k\), for Experiment 1 and state its units. [2]
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