Cambridge International A Level · Chemistry (9701)

Reaction kinetics (AS):練習問題

その場で採点される選択問題 5 問と、解説つきの記述問題 5 問。すべて「Reaction kinetics (AS)」からの出題です。

10 問25 無料・登録不要
問 1
1

What is the correct definition of activation energy, \( E_a \)?

問 2
1

The decomposition of a reactant X follows first-order kinetics. If the initial concentration of X is \(0.80 \text{ mol dm}^{-3}\) and its half-life is 20 minutes, what will the concentration of X be after 60 minutes?

問 3
1

In the oxidation of iodide ions by peroxodisulfate ions, \( S_2O_8^{2-} + 2I^- \to 2SO_4^{2-} + I_2 \), the reaction is catalysed by \( Fe^{2+}(aq) \).
Which set of equations correctly represents the homogeneous catalysis mechanism?

問 4
1

In the reaction between methane and chlorine, the first step is the homolytic fission of the \(Cl-Cl\) bond by ultraviolet light to form chlorine radicals. Which term best describes the minimum energy required for this specific step to occur effectively?

問 5
1

The reaction between hydrogen and nitrogen(II) oxide follows the rate equation: \( \text{rate} = k[NO]^2[H_2] \).
The following mechanism is proposed:
Step 1: \( 2NO \rightleftharpoons N_2O_2 \) (fast equilibrium)
Step 2: \( N_2O_2 + H_2 \to N_2O + H_2O \) (slow)
Step 3: \( N_2O + H_2 \to N_2 + H_2O \) (fast)
Why is the reaction second-order with respect to NO?

問 6
2

Define the term activation energy, \(E_a\), for a chemical reaction.

まず自分で答えを書いてから、解説と照らし合わせましょう。

問 7
4

Using the Boltzmann distribution, explain qualitatively why a small increase in temperature leads to a significant increase in the rate constant, \( k \).

まず自分で答えを書いてから、解説と照らし合わせましょう。

問 8
5

Describe the specific role of adsorption and desorption in the catalytic removal of oxides of nitrogen using a platinum-based catalytic converter in car engines.

まず自分で答えを書いてから、解説と照らし合わせましょう。

問 9
4

(a) Define the term rate of reaction. [1]
(b) Use the collision theory to explain why increasing the temperature of a reaction mixture increases the rate of reaction. [3]<\/p>

まず自分で答えを書いてから、解説と照らし合わせましょう。

問 10
5

The reaction between reactant X and reactant Y was studied at \(298\text{ K}\). The following experimental data were obtained:

ExperimentInitial [X] / \(\text{mol dm}^{-3}\)Initial [Y] / \(\text{mol dm}^{-3}\)Initial rate / \(\text{mol dm}^{-3}\text{ s}^{-1}\)
10.1500.100\(1.20 \times 10^{-4}\)
20.3000.100\(4.80 \times 10^{-4}\)
30.3000.200\(9.60 \times 10^{-4}\)

(a) Deduce the order of reaction with respect to X and the order of reaction with respect to Y. Show your reasoning. [2]

(b) Construct the rate equation for this reaction. [1]

(c) Calculate the value of the rate constant, \(k\), for Experiment 1 and state its units. [2]

まず自分で答えを書いてから、解説と照らし合わせましょう。

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